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A 6-V bias across two conductors is sufficient to induce rapid growth (readily observable with a low-power microscope) even when distilled or deionized water bridges the conductors, although growth will occur faster with tap water11 Galvanic Corrosion Galvanic corrosion occurs between dissimilar metals because they have differing affinities for electrons (ie, they are more or less electronegative) Galvanic series have been compiled for many common metals and alloys (see Table 571) Metals near the top of the series (noble metals) do not corrode; those near the bottom corrode easily When these metals are near each other, the more noble metal becomes the cathode, the less noble the anode Moisture is required to couple the two metals electrically Applied bias is generally not required, but may accelerate the reaction if the polarity is correct.

program 14-1 Implementation of LCD Use for Our Experiments (Listing of Methods Available within LCDRoutines ) {{11 Sep 09 Harprit Sandhu LCDminimal.spin Propeller Tool Ver 1.2.6 14 Program 1 PROGRAM TO BEGIN USING THE LCD A minimal LCD implementation to allow us to use the LCD in our experiments immediately. This program is an absolutely minimal implementation to make the LCD usable. You can work on improving it. We will improve it later. POWER ETC: - - BASIC CONNECTIONS 1 0 9 8 7 6 5 4 3 X X G 3 2 1 0 9 8 7 6 FOR THE EDUCATION KIT ARE STANDARD Propeller CHIP CONNECTIONS AND ARE 0 1 2 3 4 5 6 7 G B R 3 8 9 0 1 2 3 4 5 NOT SHOWN HERE 5VDC --------- G 5 G S W E 0 1 2 3 4 5 6 7 --------- 16 CHAR BY 2 LINE LCD DISPLAY GND 8 BIT MODE Schematic Revisions

When the anode is very small compared to the cathode, its corrosion can be very rapid Conversely, if the anode is much larger than the cathode, corrosion is unlikely to be serious, particularly if the difference in electronegativity is small Conductive Anodic Filament Growth Conductive anodic filament growth (CAF) causes electrical shorts when a metal that dissolves anodically is redeposited at the interface between the glass (or other) fibers and the resin matrix of a printed circuit board Conductive anodic filament growth is promoted by delamination at the glass-polymer interface, which may in turn be promoted by various environmental stresses including high temperatures (greater than about 260 C for FR-4) and thermal cycling Shorts seem to occur most rapidly when a single fiber bundle connects two pads Once delamination has occurred, the metal migration that causes shorts to occur is promoted by increasing temperature, relative humidity, and applied voltage.

Small conductor spacings also significantly decrease times to failure12 In multilayer boards, failures occur faster on outerlayers than innerlayers because the surface layer absorbs moisture more readily By the same reasoning, solder mask and conformal coating both increase the time-to-failure because they slow the absorption of moisture from the atmosphere into the board Whiskers Whiskers are faceted filament-like structures that grow spontaneously on the surface of a plated metal and can cause shorts between closely spaced conductors (see Fig 5711) Whiskering can be differentiated from other causes of shorts such as dendritic growth, because neither an electrical field nor moisture is required for whiskers to form Whiskering is a particular problem with pure tin The whiskers grow in response to internal stresses in the plating or external loads Sn whiskers are commonly 50 mm long and 1 to 2 mm in diameter..

TABLE 57.1 Standard Electromotive Force Potential (Reductions Potentials) for Elements Commonly Found in Electronic Assemblies Standard potential (Volts vs. standard hydrogen electrode) +1.498 +1.358 +1.229 +1.2 +0.799 +0.771 +0.401 +0.337 +0.15 0.000 0.126 0.136 0.250 0.440 0.744 0.828 2.714 2.925

Reaction Au3+ + 3e = Au Cl2 + 2e = 2Cl O2 + 4H+ + 4e = 2H2O (pH 0) Pt3+ + 3e = Pt Ag+ + e = Ag Fe3+ + e = Fe2+ O2 + 2H2O + 4e = 4OH (pH 14) Cu2+ + 2e = Cu Sn4+ + 2e = Sn2+ 2H+ + 2e = H2 Pb2+ + 2e = Pb Sn2+ + 2e = Sn Ni2+ + 2e = Ni Fe2+ + 2e = Fe Cr3+ + 3e = Cr 2H2O + 2e = H2 + 2OH Na+ + e = Na Active K+ + e = K Noble

Source: A. J. deBethune and N. S. Loud, Standard Electrode Potentials and Temperature Coefficients at 25C, Clifford A. Hampel, Skokie, Ill., 1964.

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